API MPMS 19.1 2017 pdf download.Manual of Petroleum Measurement Standards Chapter 19.1 Evaporative Loss from Fixed-roof Tanks.
1 Scope This standard contains methodologies for estimating the total evaporative losses of hydrocarbons from fixed-roof tanks. The methodologies provide loss estimates for general equipment types based on laboratory, test-tank, and field-tank data. Types of fixed-roof tanks and roof fittings described are for information only. The equations estimate average annual losses from fixed-roof tanks for various liquid stocks, stock vapor pressures, tank sizes, meteorological conditions, and operating conditions. The following special cases are addressed: a) horizontal tanks, b) higher volatility stocks (true vapor pressure greater than 0.1 psia), c) vent settings higher than 0.03 psia (0.5 oz/in. 2 ), d) tanks that have either roof or shell insulation. The estimation may be improved by using detailed field information, including climatic data and operational data for the appropriate time period. The equations are not intended to be used in the following applications: a) to estimate losses from unstable or boiling stocks or from petroleum liquids or petrochemicals for which the vapor pressure is not known or cannot readily be predicted [to calculate emissions from tanks that contain material at or above its boiling point or the point at which material starts to flash, the API model E&P Tank (API 4697) can be used]; b) to estimate losses from fixed-roof tanks that have an internal floating roof (API MPMS Ch. 19.2  and API 2569  address these); c) to estimate losses from cleaning fixed-roof tanks (API 2568  addresses this); d) to estimate losses from tanks with air sparging operations. The estimation procedures were developed to provide estimates of typical losses from fixed-roof tanks that are properly maintained and are in normal working condition. Losses from poorly maintained tanks may be greater.
For uninsulated tanks or for tanks with an insulated shell but an uninsulated roof, the effect of bulk liquid heating cycles on standing loss may be neglected because temperature swings in the vapor space of tanks with an uninsulated roof may be dominated by heat exchange with ambient air. Also, it can be random as to whether cycles of heating the bulk liquid add to or subtract from the vapor space temperature variation driven by the diurnal ambient temperature cycle. In a fully insulated tank, however, the temperature of the vapor space will be approximately equal to the liquid bulk temperature. Thus, if the bulk liquid is subject to cyclic heating, the vapor space will cycle through the same temperature range as the bulk liquid. Cyclic heating may occur by occasionally receiving hot stock, which then cools over time until the next receipt of hot stock, or as a result of the tank being heated by some means that is periodically turned on and off.
6.3.2 Pressure-vacuum (PV) vents are mounted on the tank roof to provide sufficient venting capacity to protect the tank from experiencing pressure or vacuum greater than the tank design pressure or vacuum, respectively. When a pressure occurs within the tank vapor space that exceeds the pressure set point, the PV vent opens to release vapors from the tank until the pressure is reduced below its set point. When a vacuum occurs within the tank vapor space that exceeds the vacuum set point, the PV vent opens to admit air into the tank until the vacuum is reduced below its set point. API 2521  describes the use of PV vents on fixed-roof tanks and presents factors to consider in their selection and maintenance. API 2000  describes the sizing requirements for PV vents on storage tanks and addresses both normal and emergency venting conditions. PV vents on atmospheric pressure fixed-roof tanks are usually set at 0.75 in. of water column, or approximately 0.5 oz/in. 2 . The required normal pressure venting capacity or vacuum venting capacity should accommodate breathing and product movement without exceeding the design pressure or design vacuum of the tank. Open vents of the mushroom or return-bend (gooseneck) type are sometimes used on fixed-roof tanks storing low-volatility liquids.